NickelMaghrebV1, Main, Exploration, bibRecord, 000210

Dilithium disodium nickel(II) cyclohexaphosphate dodecahydrate, Li2Na2NiP6O18·12H2O

Identifieur interne : 000210 ( Main/Exploration ); précédent : 000209; suivant : 000211

Dilithium disodium nickel(II) cyclohexaphosphate dodecahydrate, Li2Na2NiP6O18·12H2O

Auteurs : Sonia Abid [Tunisie] ; Salem S. Al-Deyab [Arabie saoudite] ; Mohamed Rzaigui [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.

RBID : PMC:3414093

Abstract

The crystal structure of Li₂Na₂NiP₆O₁₈·12H₂O is characterized by the presence of six-membered P₆O₁₈⁶⁻ phosphate ring anions (internal symmetry -1) having a chair conformation and three different cations, viz. Li⁺, Na⁺ and Ni²⁺, to counterbalance the anionic charge. All atoms are in general positions except for nickel, which lies on a special position with site symmetry 2. Lithium has a tetrahedral environment (LiO₄), and sodium and nickel have octahedral environments [NaO₆ and Ni(H₂O)₆, respectively]. The P₆O₁₈ rings are linked via corner sharing by NaO₆ octahedra and LiO₄ tetrahedra to form a three-dimensional framework presenting tunnels running along [010] in which the six-coordinated Ni²⁺ cations are located. The structure is stabilized by a network of O—H⋯O hydrogen bonds.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414093

DOI: 10.1107/S1600536812029960
PubMed: 22904700
PubMed Central: 3414093

Affiliations:

Arabie saoudite, Tunisie

Le document en format XML

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Na<sub>2</sub>
NiP<sub>6</sub>
O<sub>18</sub>
·12H<sub>2</sub>
O</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Dilithium disodium nickel(II) cyclohexaphosphate dodecahydrate, Li<sub>2</sub>
Na<sub>2</sub>
NiP<sub>6</sub>
O<sub>18</sub>
·12H<sub>2</sub>
O</title>
<author><name sortKey="Abid, Sonia" sort="Abid, Sonia" uniqKey="Abid S" first="Sonia" last="Abid">Sonia Abid</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
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<country xml:lang="fr">Arabie saoudite</country>
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<author><name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name>
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<front><div type="abstract" xml:lang="en"><p>The crystal structure of Li<sub>2</sub>
Na<sub>2</sub>
NiP<sub>6</sub>
O<sub>18</sub>
·12H<sub>2</sub>
O is characterized by the presence of six-membered P<sub>6</sub>
O<sub>18</sub>
<sup>6−</sup>
 phosphate ring anions (internal symmetry -1) having a chair conformation and three different cations, <italic>viz.</italic>
 Li<sup>+</sup>
, Na<sup>+</sup>
 and Ni<sup>2+</sup>
, to counterbalance the anionic charge. All atoms are in general positions except for nickel, which lies on a special position with site symmetry 2. Lithium has a tetrahedral environment (LiO<sub>4</sub>
), and sodium and nickel have octahedral environments [NaO<sub>6</sub>
 and Ni(H<sub>2</sub>
O)<sub>6</sub>
, respectively]. The P<sub>6</sub>
O<sub>18</sub>
 rings are linked <italic>via</italic>
 corner sharing by NaO<sub>6</sub>
 octahedra and LiO<sub>4</sub>
 tetrahedra to form a three-dimensional framework presenting tunnels running along [010] in which the six-coordinated Ni<sup>2+</sup>
 cations are located. The structure is stabilized by a network of O—H⋯O hydrogen bonds.</p>
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Serveur d'exploration sur le nickel au Maghreb

Dilithium disodium nickel(II) cyclohexaphosphate dodecahydrate, Li2Na2NiP6O18·12H2O

Dilithium disodium nickel(II) cyclohexaphosphate dodecahydrate, Li2Na2NiP6O18·12H2O

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Abstract

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Serveur d'exploration sur le nickel au Maghreb

Dilithium disodium nickel(II) cyclo­hexa­phosphate dodeca­hydrate, Li2Na2NiP6O18·12H2O

Dilithium disodium nickel(II) cyclo­hexa­phosphate dodeca­hydrate, Li2Na2NiP6O18·12H2O

Source :

Abstract

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Dilithium disodium nickel(II) cyclohexaphosphate dodecahydrate, Li2Na2NiP6O18·12H2O

Dilithium disodium nickel(II) cyclohexaphosphate dodecahydrate, Li2Na2NiP6O18·12H2O